At this time it is not possible to verify your identity using an expired document.
If you have been asked to enter the details of a document, but have realised that it is expired, you can proceed with an alternative document by scrolling to the bottom of your page, selecting 'back' and then answering 'no' to having that document.
For more information on the document requirements for GOV.UK Verify, please see: What documents will I need to prove my identity?